][(1R,2R)-2-(diphenyL - Names and Identifiers
Name | Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate
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Synonyms | ][(1R,2R)-2-(diphenyL phosphino)-1,2-diphenyL ethanamine]ruthenium(II) tetrafL Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II)tetra Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate
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CAS | 1150112-54-1
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][(1R,2R)-2-(diphenyL - Physico-chemical Properties
Molecular Formula | C70H55B2ClF8NP3Ru
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Molar Mass | 1313.2459086 |
Appearance | solid |
Color | orange to brown |
Storage Condition | 2-8 ℃, dark, nitrogen storage |
Sensitive | air sensitive |
][(1R,2R)-2-(diphenyL - Introduction
Chloro[(R)-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate (also known as Ru-BINAP) is an organic complex containing ruthenium metal. It has the following properties, uses, methods and safety information:
Nature:
- Ru-BINAP is a golden solid.
-It is soluble in many organic solvents at room temperature, such as ether, methanol and dichloromethane.
- Ru-BINAP is not easily soluble in water.
Use:
- Ru-BINAP are widely used to catalyze organic synthesis reactions.
-It can be used as an asymmetric catalyst to promote the progress of asymmetric synthesis.
- Ru-BINAP can catalyze asymmetric hydrogenation, asymmetric carbonyl reduction, cycloaddition and other reactions.
Preparation Method:
- Ru-BINAP can be prepared by reacting [RuCl₂(bipy)] (bipy is 2,2 '-bipyridine) with 2,2'-bis(diphenylphosphino)-1,1 '-binaphthyl(BINAP) and (1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine.
-Specific synthetic methods can refer to the relevant literature and professional literature.
Safety Information:
- Ru-BINAP are usually low toxic in catalytic reactions, but still need to follow the general laboratory safety practices.
-When using Ru-BINAP, avoid contact with skin and eyes.
-When storing and handling Ru-BINAP, care should be taken to prevent it from coming into contact with moisture, oxygen and other oxidants in the air.
-Need to operate under well-ventilated conditions to avoid inhalation of vapor or dust.
- Ru-BINAP should be stored in a dry, sealed container, away from fire and flammable materials.
It should be noted that research and use Ru-BINAP should follow relevant safety operations and instructions. For specific safety information and operating procedures, please refer to the relevant safety data sheet (MSDS) or contact chemical laboratory professionals.
Last Update:2024-04-09 19:05:53